A book on video game geometry is probably not going to help your brother much. It will talk about mathematics topics used in video games, not necessarily those covered in his curriculum, and may entirely skip over certain things he needs to know to pass his subjects.
Plus, just because it's related to video games doesn't mean it's going to be fun - it's a maths book either way.
Have you tried pointing your brother to Khan Academy?
It containsIt's a free (as in Wikipedia) library of lectures which cover, among other things, almost every topic in the entire American school curriculum and has an entire section devoted toincluding geometry. They're short and explained in a way that's quite easy to understand. If your brother is struggling because he doesn't quite understand how to do things, rest assured the Khan Academy's lectures have short and easyhe'll be able to understand explanations of just about everythinglearn from Khan Academy.